Syllabus 525

SURFACE PROPERTIES OF MATERIALS 635:525 Professor Garofalini Rm. A217; shg@rutgers.edu

NOTE: CERTAIN LATER TOPICS MAY BE MOVED FORWARD BASED ON INTERESTS

COURSE DESCRIPTION:

Introduction to the properties of surfaces and interfaces formed in materials. Topics include surface thermodynamics, the structure of surfaces, kinetic processes occurring at surfaces, and experimental techniques for analyzing surfaces. Examples and applications will be included.

All class notes and materials from this class are protected by copyright laws. See below (page bottom).
TOPIC READING* HOMEWORK  
1. Thermodynamics of surfaces and surface terminology

Blakely pgs 1-6

   
2. Surface tension vs. surface stress

Hudson

   
3. Gibbs-Thomson relation, Young-Laplace equation

Blakely pgs 24-29

Kelvin Eq

   
4. Effect of orientation on surface energy and structure, Wulff plot, Herring equations

 

   
5. Experimental measurements of surface tension

 

   
6. Surface analysis techniques

Brundel,

Rudd-STM-XPS

HW 1 due Sept 24

HW 2 due Sept 24

 
7. Surface structure and composition

 

HW 3 due Oct 8  
8. Multicomponent systems

Multicomponent

HW 4 due Oct 29  
9. Surface segregation

Mackrodt

Wynblatt

HW 5 due Oct 29  
10. Atomistic processes at surfaces; Adsorption Diffusion

 

HW 6 due Dec 3  
11.  Intergranular films (IGFs) in ceramics

 

   

TABLE1-all energy levels and photons

Selected Reading from:

Introduction to the Properties of Crystal Surfaces, J. M. Blakely

Encyclopedia of Materials Characterization, C. R. Brundel, C. A. Evans, and S. Wilson

Surface Science: An Introduction, J. Hudson

Additional Reading on Specific Techniques or Topics

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